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27권 12호 957-964 2019 [한국자동차공학회 논문집 ]

제목 탈질 시스템 환원제 공급을 위한 바이오 에탄올 건식개질 촉매 개발
분야 연료 및 배기
언어 Korean
저자 이동석(한국화학연구원), 이성훈(한국화학연구원), 이진희(한국화학연구원), 장태선(한국화학연구원), 허일정(한국화학연구원), 한명완(충남대학교)
Key Words DeNOx(탈질), Syngas(합성가스), CO2 dry reforming(CO2 건식 개질), Ethanol(에탄올), Ni based catalyst(니켈기반 촉매), Coke resistance(탄소침적 저항성)
초록 A study was carried out on CO2 reforming catalysts using ethanol based on biofuels for the production of syngas(CO, H2), a reducing agent for NOx reduction. Ni catalyst in various supports, such as -Al2O3, MgO-Al2O3, SiO2, CeO2, ZrO2, showed great synthetic gas production capability, and through evaluation, resistance to performance and carbon impaction was compared. The performance assessments of the catalyst were carried out by lowering the temperature to a 50 °C range from 850 °C to 700 °C. The reaction products were analyzed via IR. The characterization of the catalysts were performed through BET, XRD, and TPR, and TG analysis was performed to check the amount of deposited coke in catalysts after the reaction. In this study, Ni/MgO-Al2O3 showed an enhanced performance on carbon deposition.
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