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28권 4호 271-275 2020 [한국자동차공학회 논문집 ]

제목 메탄 전환 성능 향상을 위한 Pt-Pd 기반 촉매 개발
분야 연료 및 배기
언어 Korean
저자 박지석(광주과학기술원), 이동석(한국화학연구원), 이재홍(한국화학연구원), 허일정(한국화학연구원), 강성봉(광주과학기술원)
Key Words Methane conversion(메탄 전환), Oxidation catalyst(산화 촉매), PGM ratio(귀금속 비율), Reaction condition(반응 조건)
초록 The complete oxidation of methane under realistic feed conditions containing water vapor normally requires high reaction temperatures above 500 °C over the typical platinum group metal(PGM)-based catalysts. A Pt-Pd bimetallic catalyst was developed to improve the low-temperature oxidation performance of methane under various oxygen concentration levels in the feed. The PGMs supported by alumina catalysts were prepared as a function of Pt:Pd ratio(1:0, 1:1, and 0:1) through the wet-impregnation method. The Pt:Pd-1:1 catalyst showed better oxidation activity than the Pd-only and Pt-only catalysts, where the better performance of the Pt:Pd-1:1 bimetallic catalyst appears to be on account of the superior steam reforming activity by Pt and the intrinsic oxidation activity by Pd.
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